Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 25, Pages 8534-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1029045
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Funding
- NIH [K99GM084302, 5ROIGM-31332]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0809418] Funding Source: National Science Foundation
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The relative TONs of productive and nonproductive metathesis reactions of diethyl diallylmalonate are compared for eight different ruthenium-based catalysts. Nonproductive cross metathesis is proposed to involve a chain-carrying ruthenium methylidene. A second more-challenging substrate (dimethyl allylmethylallylmalonate) that forms a trisubstituted olefin product is used to further delineate the effect of catalyst structure on the relative efficiencies of these processes. A steric model is proposed to explain the observed trends.
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