Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 43, Pages 15102-15103Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105986b
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Funding
- National Natural Science Fund for Distinguished Young Scholars of China [20725101]
- NNSF of China [50872133]
- NSF of Fujian Province [E0510030]
- 973 Program [2011CB-932504]
- CAS
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Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni-6-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate organic molecular cage with high thermal and hydrothermal stability.
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