Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 26, Pages 8900-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja103426d
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Funding
- NCET [NCET-06-0711]
- NSFC [20872112]
- Hunan Provincial Innovation Foundation For Postgraduate [CX2009B104]
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A new, efficient Cu-catalyzed intramolecular C-H oxidation/acylation method has been developed for the synthesis of substituted indoline-2,3-diones (isatins). In the presence of CuCl, and O-2, a variety of formyl-N-arylformamides underwent the tandem reaction to afford the corresponding indoline-2,3-diones in moderate to good yields. It is noteworthy that the reaction serves as the first example of transition-metal-catalyzed transformation for the preparation of indoline-2,3-diones.
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