Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 29, Pages 10018-10020Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja104386g
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- Deutsche Forschungsgemeinschaft (DFG)
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Reaction of IPr.SiCl2 (1) [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene] with 1-azidoadamantane leads to functionalized N-heterocyclic carbene (NHC) 2. Silyl-substituted NHC 2 reacts easily with 1-azidoadamantane to form triazene 3, in which the exocyclic C=N bond is slightly shorter than those of regular NHC-derived triazines. 2 could serve as a promising ligand for transition metals.
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