Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 20, Pages 6920-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja101586w
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- Research Grants Council of the HKSAR, the People's Republic of China [CUHK 400307]
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The aliphatic carbon-carbon activation of c-octane was achieved via the addition of Rh(ttp)H to give Rh(ttp)(n-octyl) in good yield under mild reaction conditions. The aliphatic carbon-carbon activation was Rh-II(ttp)-catalyzed and was very sensitive to porphyrin sterics.
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