4.8 Article

Bis[3-(5-nitroimino-1,2,4-triazolate)]-Based Energetic Salts: Synthesis and Promising Properties of a New Family of High-Density Insensitive Materials

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 34, Pages 11904-11905

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja1055033

Keywords

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Funding

  1. DTRA [HDTRA1-07-1-0024]
  2. NSF [CHE-0315275]
  3. ONR [N00014-10-1-0097]
  4. NSFC [20971122]

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Bis[3-(5-nitroimino-1,2,4-triazolate)]-based energetic salts were synthesized in a simple, straightforward manner. They exhibit low solubility in available solvents, high hydrolytic stability, excellent thermal stability, high density, positive heat of formation, low shock sensitivity, and excellent detonation properties. The physical and energetic properties of some salts are similar and even superior to those of RDX.

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