4.8 Article

Water Hydrogen Bond Structure near Highly Charged Interfaces Is Not Like Ice

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 20, Pages 6867-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja910914g

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Funding

  1. MEXT [19056009]
  2. JSPS [19205005]
  3. Grants-in-Aid for Scientific Research [19205005, 19056009] Funding Source: KAKEN

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Imaginary x((2)) spectra of HOD at air/charged surfactant/aqueous interfaces highly resemble the IR spectrum of the bulk liquid HOD, showing no indication of the ice-like structure. Clearly, the hydrogen bond structures at highly charged interfaces are not like ice but very similar to the structure in the bulk.

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