Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 26, Pages 8872-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja103982t
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Funding
- National Science Foundation [CHE-0952083]
- American Chemical Society Petroleum Research Fund [49646-DN13]
- Cambridge Isotope Laboratories, Inc
- University of Cincinnati University Research Council
- NSF-MRI [CHE-0215950]
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Nickel hydride with a diphosphinite-based ligand catalyzes the highly efficient reduction of CO(2) with catecholborane, and the hydrolysis of the resulting methoxyboryl species produces CH(3)OH in good yield. The mechanism involves a nickel formate, formaldehyde, and a nickel methoxide as different reduced stages for CO(2). The reaction may also be catalyzed by an air-stable nickel formate.
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