Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 47, Pages 16730-16732Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja106798a
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- Ministry of Education, Culture, Sports, Science and Technology
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The reaction between H2O2 and a pyridine-coordinated ferric porphyrin encapsulated by a cyclodextrin dimer yielded a hydroperoxoferric porphyrin intermediate, PFeIII-OOH, which rapidly decomposed to oxoferryl porphyrin (PFeIV=O). Upon reaction with H2O2, PFeIV=O reverted to PFeIII-OOH, which was converted to carbon monoxide-coordinated ferrous porphyrin under a CO atmosphere. PFeIV=O in the presence of excess H2O2 behaves as PFeIII-OOH.
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