Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 32, Pages 10998-10999Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105021d
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Funding
- National Natural Science Foundation of China [20725205]
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Stable compounds with a boron-chalcogen (S or Se) valence double bond have been prepared via sequences involving insertion of the chalcogen into a B-H bond and subsequent hydrogen migration. X-ray diffraction studies and density functional theory calculations on the resulting compounds provide convincing evidence for the boron-chalcogen multiple bonding.
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