Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 48, Pages 17062-17064Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja106903p
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Funding
- NSF [DMR-0846958]
- DOE [ER46631, DE-SC0002235]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0846958] Funding Source: National Science Foundation
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The integration of negatively charged single-metal building blocks {In(CO2)(4)} and positively charged trimeric clusters {ln(3)O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.
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