4.8 Article

Pore Space Partition and Charge Separation in Cage-within-Cage Indium Organic Frameworks with High CO2 Uptake

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 48, Pages 17062-17064

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja106903p

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Funding

  1. NSF [DMR-0846958]
  2. DOE [ER46631, DE-SC0002235]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Materials Research [0846958] Funding Source: National Science Foundation

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The integration of negatively charged single-metal building blocks {In(CO2)(4)} and positively charged trimeric clusters {ln(3)O} leads to three unique cage-within-cage-based porous materials, which exhibit not only high hydrothermal, thermal, and photochemical stability but also attractive structural features contributing to a very high CO2 uptake capacity of up to 119.8 L/L at 273 K and 1 atm.

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