4.8 Article

High Triplet Yield from Singlet Fission in a Thin Film of 1,3-Diphenylisobenzofuran

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 46, Pages 16302-16303

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja104123r

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Funding

  1. U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy [XAT-5-33636-01, DE-FG36-08GO18017]
  2. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences, and Geosciences [DE-AC36-08GO28308]

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Direct observation of triplet absorption and ground-state depletion upon pulsed excitation of a polycrystalline thin solid film of 1,3-diphenylisobenzofuran at 77 K revealed a 200 +/- 30% triplet yield, which was attributed to singlet fission.

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