Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 25, Pages 8536-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja102753d
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Funding
- Alexander von Humboldt Foundation
- Max-Planck-Society
- DFG [SPP1179]
- Fonds der Chemischen Industrie
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A catalytic enantioselective transacetalization has been developed. The chiral phosphoric acid TRIP was demonstrated to be an efficient and highly enantioselective catalyst for the activation of O,O-acetals. The reaction enables the asymmetric synthesis of acetals with the acetal carbon as the only stereogenic center.
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