Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 8, Pages 2524-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja910582n
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Funding
- Robert A. Welch Foundation
- NIH [GM31278, DK38226]
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Scalemic alpha-cyanohydrin triflates undergo Pd-catalyzed cross-coupling with aryl, heteroaryl, and vinyl boronic acids under mild conditions. Coupling proceeds with complete inversion of configuration at the stereogenic carbon. The resultant nitrile can be easily converted into a variety of alternative functional groups of value in organic synthesis and thus achieves a higher level Of Molecular complexity than the products of traditional Suzuki reactions.
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