Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 17, Pages 5956-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja101671q
Keywords
-
Categories
Funding
- NFSC [20871073, 20921001, 20373001]
- THSJZ
- Key Laboratory of Polyoxometalate Science of the Ministry of Education of China
Ask authors/readers for more resources
The first polyoxometalatocyclophanes have been synthesized by the covalent linkage of a hexamolybdate cluster and bisarylimido ligands containing flexible chains. These metallamacrocycles are chiral, and some of them can undergo spontaneous resolution. The work provides a new protocol for preparing chiral polyoxometalates (POMs) and chiral metallamacrocycles from achiral building blocks by fastening both ends of a flexible chain onto an achiral POM to remove the symmetric center and mirror.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available