Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 40, Pages 13992-13993Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105537j
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Funding
- The University of Hong Kong
- URC
- University Grants Committee [AoE/P-03/08]
- Hong Kong UGC [SEG HKU09]
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A versatile dithienylethene-containing beta-diketonate ligand and its boron(III) compounds have been successfully synthesized. Upon photocyclization, the ligand shows a new absorption band at 630 nm with good fatigue resistance and high thermal stability. Incorporation of the boron center has been demonstrated to shift the photochromic behavior to the NIR region.
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