4.8 Article

Tripodal exTTF-CTV Hosts for Fullerenes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 15, Pages 5351-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja1006993

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A receptor for fullerenes featuring three exTTF units linked to a CTV scaffold is described. The exTTF-CTV host forms remarkably stable complexes with both C-60 (log K-a = 5.3 +/- 0.2) and C-70 (log K-a = 6.3 +/- 0.6). Light-induced ESR spectra demonstrate that intracomplex PET processes take place in solution.

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