4.8 Article

A Bis-exTTF Macrocyclic Receptor That Associates C60 with Micromolar Affinity

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 6, Pages 1772-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja910107m

Keywords

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Funding

  1. MICINN of Spain [CTQ2008-00795/BQU, CTQ2006-14987-C02-02/BQU, CSD2007-00010]
  2. ESF [MAT2006-28170-E]
  3. CAM [MADRISOLAR-2 S2009/PPQ-1533]
  4. Generalitat Valenciana [ACOMP/2009/269]
  5. European FEDER
  6. Ramon y Cajal Fellowship
  7. European Social Fund

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An exTTF-based macrocyclic receptor that associates C-60 with a binding constant > 10(6) M-1 in chlorobenzene at room temperature is described. This represents an improvement of 3 orders of magnitude with respect to the previous examples of exTTF-based receptors and one of the highest binding constants toward C-60 reported to date.

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