Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 5, Pages 1512-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja909726h
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- Organic Chemistry Institute of the University of Zurich
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A novel gold-catalyzed ethynylation of aromatic rings with electron-deficient alkynes via gold catalyzed C-H activation of both C-sp-H and C-sp(2)-H bonds has been developed. This transformation provides aromatic propiolates difficult to prepare by other methods, highlighting the synthetic potential of gold chemistry.
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