Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 26, Pages 8888-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja103935q
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Funding
- Defense Threat Reduction Agency [HDTRA1-07-1-0024]
- National Science Foundation [CHE-0315275]
- Office of Naval Research [N00014-06-1-1032]
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The first silver-FOX, silver-ammonia-FOX, and silver-amine-FOX compounds were synthesized by the reactions of silver nitrate with K-FOX or guanidine-FOX in water, aqueous ammonia, and amines, respectively. The crystal structure of silver-ammonia-FOX exhibits unique covalent bonding behavior, which is supported by NBO calculations.
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