Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 46, Pages 16362-16364Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja107843b
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Funding
- 973 Program [2006CB300402, 2007CB815307]
- NSFC [20821003, 20702053, 20973137, 20673088, 20425312, 20721001, 20423002]
- Ministry of Science and Technology [2008ZX05013-004]
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The endohedral fullerene Sc3NC@C-80-I-h has been synthesized and characterized; it has an unprecedented planar quinary cluster in a fullerene cage. It is also the first chemical compound in which the presence of an unprecedented (NC)(3-) trianion has been disclosed. The fascinating intramolecular dynamics in Sc3NC@C-80-I-h enables the whole molecule to display high polarity and promising ferroelectricity. This finding inspires the possibility that such a planar quinary cluster may be useful in constructing many other endohedral fullerenes.
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