Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 33, Pages 11414-11415Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105048c
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Funding
- MEXT [16750073, 18065007]
- Asahi Glass Foundation
- Grants-in-Aid for Scientific Research [18065007, 22225004, 16750073] Funding Source: KAKEN
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Highly enantioselective hydrogenative desymmetrization of bicyclic imides has been developed with chiral (CpRu)-Ru-star(PN) catalysts. The present hydrogenation directly provides stereochemically well-defined cyclic compounds with excellent enantiomeric exessses, which might otherwise require a detour to reach.
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