4.8 Article

Chiral Kagome Network from Thiacalix[4]arene Tetrasulfonate at the Interface of Aqueous Solution/Au(111) Surface: An in Situ Electrochemical Scanning Tunneling Microscopy Study

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 16, Pages 5598-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja101598p

Keywords

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Funding

  1. National Natural Science Foundation of China [20733004, 20821003, 20821120291]
  2. National Key Project on Basic Research [2006CB806100, 2006CB932014, 2009AA034200]
  3. Chinese Academy of Sciences

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A chiral Kagome network was fabricated at an aqueous solution/Au(111) interface by using a complicated stereo supramolecule thiacalix[4]arene tetrasulfonate as a building block. It opens the possibility to construct a 2D nanoporous network by various functional supramolecules and shows potential application in host-guest chemistry as well as chiral resolution.

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