Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 40, Pages 14061-14063Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja107160g
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Funding
- Ministry of Education, Science, Sports, and Culture of Japan [19105001, 21350023, 21108502]
- Grants-in-Aid for Scientific Research [19105001, 21108502, 21350023] Funding Source: KAKEN
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The reaction of disilyne 1 with 1,3,4,5-tetramethylimidazol-2-ylidene (an N-heterocyclic carbene, NHC) produced the disilyne-NHC complex 2, RLSi=SiR: (R = (SiPr)-Pr-i[CH(SiMe3)(2)](2), L = NHC), with a trans geometry of the Si-Si moiety and lone-pair electrons residing on one of the double-bonded Si atoms. Upon complexation of 2 with ZnCl2, the disilyne-NHC-ZnCl2 complex 3 was produced, in which the Si-Si bond adopted the cis geometry.
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