Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 1, Pages 275-280Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja906996c
Keywords
-
Categories
Funding
- Novartis
- Taiho Pharmaceutical Co., Ltd.
Ask authors/readers for more resources
This Article describes an enantioselective synthesis of cephalostatin 1. Key steps of this synthesis are a unique methyl group selective allylic oxidation, directed C-H hydroxylation of a sterol at C12, Au(I)-catalyzed 5-endo-dig cyclization, and a kinetic spiroketalization.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
