Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 46, Pages 16321-16323Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja106172d
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Funding
- FCI
- European Phosphorus Science Network [CM0802]
- International Research Training Group (IRTG) [1444]
- DFG [WE 4621/2-1]
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A versatile, high-yield ng synthesis of NHC-stabilized [PCI2](+) and [PCI](2+) phosphorus synthons has been achieved by using an onio-substituent transfer reagent. Subsequent functionalization yields access to cationic cyano- aid azido-substituted derivatives which represent first examples of a displacement read:ion on NHC-stabilized phosphorus(III)-centered cations. The new salts have been fully characterized by NMR spectroscopy and X-ray crystallography.
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