Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 41, Pages 14400-14402Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja107185w
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Funding
- NSF [CHE-0614798]
- U.S.-Israel Binational Science Foundation
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Monohydrocarbyl palladium(IV) complexes bearing OH, OH2, Br, and Cl ligands at the metal and supported by facially chelating 1-hydroxy-1,1-bis(2-pyridyl)methoxide were readily prepared in water at 0 degrees C. These complexes reductively eliminate Ar-X (X = OH, Br, Cl) in water at room temperature in high yield, and the corresponding first-order rate constants k(OH), k(Cl), and k(Br) are on the same order of magnitude.
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