Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 33, Pages 11418-11419Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105111n
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Funding
- NSFC [20872159, 20821002, 20923005]
- National Basic Research Program of China (973 Program) [2009CB825300]
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With 2-methyl-1,2,3,4-tetrahydroquinoline-derived phosphoramidite ligand (R,R(a))-L(6), Ir-catalyzed intramolecular C-3 allylic alkylation of indoles has been realized to afford highly enantioenriched spiroindolenine derivatives in 92-98% yields with up to >99/1 dr and 97% ee.
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