4.8 Article

Nonclassical Active Site for Enhanced Gas Sorption in Porous Coordination Polymer

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 19, Pages 6654-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja1009635

Keywords

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Funding

  1. NSFC [20821001, 90922031]
  2. 973 Project [2007CB815302]
  3. Chinese Ministry of Education [109125]

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Gas sorption experiments and grand canonical Monte Carlo simulations for two isostructural microporous metal azolate frameworks show that even partially exposed uncoordinated nitrogens can effectively increase gas binding affinity and overcome the pore size confinement effect.

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