4.8 Article

Enantioselective Synthesis of Allylic Esters via Asymmetric Allylic Substitution with Metal Carboxylates Using Planar-Chiral Cyclopentadienyl Ruthenium Catalysts

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 4, Pages 1206-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja908456b

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [20037042]
  2. Grants-in-Aid for Scientific Research [20037042] Funding Source: KAKEN

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An asymmetric allylic substitution with sodium carboxylate using a planar-chiral cyclopentadienyl ruthenium complex has been developed. Optically active allylic esters were prepared in good yields with high regio- and enantioselectivities.

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