Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 3, Pages 914-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja909038t
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Funding
- Institute of Bioengineering and Nanotechnology (Biomedical Research Council, Agency for Science, Technology and Research, Singapore
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The catalytic reduction of carbon dioxide to carbon monoxide Under mild conditions Using aromatic aldehydes as reductants and NHCs as organocatalysts was developed. This carbon dioxide splitting reaction provides a new method for metal-free carbon dioxide reduction and Steps forward in utilizing carbon dioxide as a renewable green source under mild conditions. On the other hand, this reaction also shows a new economical way to oxidize aromatic aldehydes under mild conditions with carbon dioxide and could be applied in pharmaceutical synthesis.
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