Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 10, Pages 3246-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja910076n
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- National Science Foundation [CHE-0718117]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1012578] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0718117] Funding Source: National Science Foundation
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The radical cation of carbon sulfur [7]helicene is configurationally stable in solution at room temperature. In contrast to the radical cations of alpha-oligothiophenes, which form diamagnetic pi-dimers at low temperature, the radical cation of this helical, cross-conjugated beta-oligothiophene shows a low propensity toward dimerization.
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