Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 34, Pages 11893-11895Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105263q
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Funding
- Royal Commission
- EPSRC
- Clarendon Fund
- Trinity College
- Diamond Light Source [MT1858]
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We report the first use of solution-phase halogen bonding to control and facilitate the assembly of an interlocked structure through the bromide anion-templated formation of a rotaxane based upon an iodotriazolium axle. The incorporation of a halogen atom into the rotaxane host cavity dramatically improves the anion-recognition capabilities of the interlocked receptor, giving unusual iodide selectivity in a competitive aqueous medium.
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