4.8 Article

A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 1, Pages 30-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja908794n

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Funding

  1. KAKENHI [20044006]
  2. JSPS
  3. Global COE Program
  4. MEXT, Japan
  5. Photon Factory Program Advisory Committee [2008G052]
  6. Grants-in-Aid for Scientific Research [20044006] Funding Source: KAKEN

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All-trans retinal efficiently diffused into the pore of a porous coordination network consisting of Znl(2) and an electron-deficient triazine-cored ligand. Enclathrated retinal was isomerized into the 13-cis form and easily replaced with all-trans retinal in solution, thus revealing the catalysis of retinal isomerization by the porous network.

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