Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 45, Pages 15836-15838Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105541r
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- MEXT [22106520]
- Grants-in-Aid for Scientific Research [22106520] Funding Source: KAKEN
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The enantioselective intermolecular [2 + 2 + 2] cycloaddition reaction of two molecules of isocyanate and one molecule of allene is catalyzed by a nickel(0)/(S,S)-i-Pr-FOXAP complex, providing an efficient access to enantiomerically enriched dihydropyrimidine-2,4-diones.
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