Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 32, Pages 11002-11003Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja105314x
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [20108010, 21750146]
- KOSEF/MEST through WCU [R31-2008-000-10010-0]
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Photoexcitation of gold nanoclusters covalently functionalized with 9-mesityl-10-methylacridinium ion (Mes-Acr(+)) resulted in the formation of the electron-transfer state (Mes(center dot+)-Acr(center dot)), which forms a pi-dimer radical cation with the neighboring Mes-Acr(+) via an intramolecular pi-pi a interaction.
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