Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 29, Pages 9992-9993Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja104842h
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Funding
- MEXT, Japan [18685013, 20037034]
- Asahi Glass Foundation
- JSPS
- Grants-in-Aid for Scientific Research [21685011, 18685013, 20037034] Funding Source: KAKEN
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Highly stable eta(2)-porphyrin Ru(II) pi complexes have been synthesized. The formation of the eta(2) pi it bond has been facilitated through pi-pi stacking interactions between the porphyrin and the planar ligand on Ru. pi coordination of ruthenium to porphyrin results in dramatic changes in the aromaticity and electronic properties. These properties are controllable via fine-tuning of the ligand on ruthenium.
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