Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 29, Pages 10006-10008Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja104004t
Keywords
-
Categories
Ask authors/readers for more resources
The layered telluride, Fe1+xTe, is a parent compound of the isostructural and superconducting phases, Fe1+x(Te, Se, S). Here we show that, through a simple reaction of 12 vapor with both powder and single crystal samples, the interstitial iron can be removed from the FeTe framework topotactically. Neutron powder diffraction and X-ray single crystal diffraction confirm that the iron being extracted is the partially occupied site that lies between the 2-D blocks of edge-sharing FeTe4 tetrahedra. The deintercalation process has consequences for both magnetic and crystallographic phase transitions in the compound at low temperatures. This technique could be of use for the tuning of stoichiometry of the superconducting phases and therefore enable more careful studies on how chemical composition affects magnetic and superconducting properties.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available