Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 6, Pages 1802-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja910831k
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Funding
- NIH [GM57859]
- Merck, Inc
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A convergent synthesis of(-)-crambidine is reported. The sequence Capitalizes on two novel key transformations, including.(I) a [4+2] annulation of thioimidates with vinyl carbodiimides and an alkyne hydroamination employing 2-aminopyrimidine nucleophiles.
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