Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 5, Pages 1492-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja909596a
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Funding
- National Natural Science Foundation of China [20825724, 50943048]
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A new type of heterogenized organometallic catalysts, periodic mesoporous organometallic silicas with organometals and organic groups embedded in silica walls have been developed using surfactant-directed co-condensation. These catalysts exhibit high efficiencies and strong durability in water-medium organic reactions. Moreover, a bifunctional catalyst containing both Pd(II) and Ru(II) organometals inside pore walls can catalyze the water-medium one-pot cascade reaction effectively. These catalysts can be conveniently recycled and reused without significant loss of catalytic activities.
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