4.8 Article

Nickel-Catalyzed Alkenylative Cross-Coupling Reaction of Alkyl Sulfides

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 38, Pages 13117-13119

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja104155f

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology Japan (MEXT)
  2. Japan Society for the Promotion of Science (JSPS) [20675003, 21750098]
  3. Tosoh Finechem
  4. Tosoh Corporations
  5. Noguchi Institute
  6. Grants-in-Aid for Scientific Research [21750098] Funding Source: KAKEN

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A novel cross-coupling reaction of alkyl aryl sulfides with aryl Grignard reagents has been achieved to produce the alkenyl-aryl coupling products in high yields by using catalytic Ni(cod)(2) and a bulky N-heterocyclic carbene ligand, SIPr.

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