Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 8, Pages 2573-2584Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9082733
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Funding
- Ministere de la Jeunesse, de l'Education nationale et de la Recherche
- College de France
- CNRS [UMR 7006]
- Universite de Strasbourg
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Dynamic glycopolymers have been generated by polycondensation through acylhydrazone formation between components bearing lateral bioactive oligosaccharide chains. They have been characterized as bottlebrush type by cryo-TEM and SANS studies. They present remarkable fluorescence properties whose emission wavelengths depend on the constitution of the polymer and are tunable by constitutional modification through exchange/incorporation of components, thus also demonstrating their dynamic character. Constitution-dependent binding of these glycodynamers to a lectin, peanut agglutinin, has been demonstrated.
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