Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 46, Pages 16358-16361Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1074322
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- U.S. Department of Energy [DE-SC0000989]
- U.S. Department of Energy (DOE) [DE-SC0000989] Funding Source: U.S. Department of Energy (DOE)
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Millimeter-sized single MOF-5 crystals are used as chromatographic columns to effectively separate mixtures of organic dyes. Remarkably, owing to the nanoscopic pore dimensions and the molecular-level interactions between the migrating molecules and the MOF scaffold, the separations occur over a distance of only a few hundred micrometers which is unambiguously confirmed by fluorescence confocal microscopy.
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