Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 7, Pages 2166-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja910139a
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Funding
- EPSRC
- Royal Society
- Engineering and Physical Sciences Research Council [EP/E012949/1] Funding Source: researchfish
- EPSRC [EP/E012949/1] Funding Source: UKRI
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Addition of excess sterically stabilized P2VP latex to a colloidal dispersion of P2VP-silica nanocomposite particles (with silica shells at Full monolayer coverage) leads to the facile redistribution Of the silica nanoparticles such that partial coverage of all the P2VP latex particles is achieved. This silica exchange. which is complete within I h at 20 degrees C as judged by small-angle x-ray scattering, is observed for nanocomposite particles prepared by heterofluocculation, but not for nanocomposite particles prepared by in situ copolymerization. These observations are expected to have important implications for the optimization of nanocomposite formulations in the coatings industry.
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