Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 132, Issue 13, Pages 4566-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja1009426
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Funding
- National Science Foundation [CHE-0748982, CHE-0518510, CHE-0541766]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0748982] Funding Source: National Science Foundation
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The syntheses of benzoxaphospholes and new benzobisoxaphospholes that display blue fluorescence are presented. The latter compounds were accessed by the use of a new precursor, 2,5-diphosphinohydroquinone. The new compounds were fully characterized, including a structural study of 2,6-tert-butylbenzo[1,2-d;4,5-d']bisoxaphosphole. Quantum yields for photoluminescence were determined for a series of compounds. These materials feature bona fide P=C p-p pi bonds suitable for conjugated materials having phosphorus as a participatory atom and can thus photocopy the properties of other conjugated organic molecules.
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