Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 40, Pages 14168-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja903574e
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- MEXT, Japan
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Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3 500 000 and a turnover frequency of 150 000 h(-1), both of which are the highest values reported to date.
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