Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 33, Pages 11658-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja903923s
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Funding
- NSFC [20537010, 20603007]
- NCET [07-0192]
- 973 Program [2007CB613306]
- AvH Foundation
- ENERCHEM
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A bioinspired iron-based catalyst with semiconductor photocatalytic functions in combination with a high surface area holds promise for synthetic chemistry via combining photocatalysis with organosynthesis. Here exemplified for phenol synthesis, Fe-g-C3N4/SBA-15 is able to oxidize benzene to phenol with H2O2 even without the aid of strong acids or alkaline promoters. By taking advantage of both catalysis and photocatalyisis functions of g-C3N4 nanoparticles, the yield of the phenol. can be markedly promoted.
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