Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 51, Pages 18257-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja907900b
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Funding
- Hong Kong Research Grants Council [CUHK 402408]
- Wei Lun Foundation
- Chinese University of Hong Kong
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Surface functionalization of polyoxometalate anions with silver(I) tert-butylethynide in an organic solution medium has been achieved for the first time using an acid-induced facile approach. The generated neutral hybrid monomeric complexes [Ag-40(C (CBu)-Bu-t)(22)(CF3COO)(12)(V10O28)]center dot 4CH(3)OH (1) and [Ag-40(C (CBu)-Bu-t)(20)(CF3COO)(12)(Mo6O22)]center dot 2CH(3)OH (2) constitute members of a new silver(I)-polyoxometalate family in which the polyoxometalate anion is embedded in a polyhedral silver(I) cluster assembled by multiple argentophilic Ag center dot center dot center dot Ag interactions.
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