4.8 Article

Molecular Recognition of Pyridine N-Oxides in Water Using Calix[4]pyrrole Receptors

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 9, Pages 3178-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja900151u

Keywords

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Funding

  1. MEC, Spain [CTQ2005-08989C02/BQU, CTQ2008-00222/BQU]
  2. Consolider Ingenio 2010 Grant [CSD2006-0003]
  3. ICIQ Foundation
  4. Generalitat de Catalunya [2005SGR00108]
  5. ICREA Funding Source: Custom

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The incorporation of four carboxylic acids or four amino groups to the upper rim of an aryl extended calix[4]pyrrole produces water-soluble receptors which are able to effectively bind aromatic N-oxides in water by a combination of hydrogen bonding, pi-pi, CH-pi, and hydrophobic interactions.

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