Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 44, Pages 16048-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9048702
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- KAKENHI [18105004]
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A new solution-processable fabrication protocol using a soluble tetrabenzoporphyrin (BP) precursor and bis(dimethylphenylsilylmethyl)[60]fullerene (SIMEF) created three-layered p-i-n photovoltaic devices, in which the i-layer possesses a well-defined bulk heterojunction structure in which columnar BP crystals grow vertically from the bottom p-layer. The device showed a power conversion efficiency of 5.2% (V-oc = 0.75 V; J(sc) 10.5 mA/cm(2); FF = 0.65).
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